Sandvik Materials Technology is a developer and producer of advanced stainless steels, special alloys, titanium and other high-performance materials

Sanicro 28 for OCTG (Tube and pipe, seamless)

Datasheet updated 2012-11-22 09:20:01 (supersedes all previous editions)

Sanicro 28 is a high-alloy austenitic stainless steel for OCTG downhole applications in particularly corrosive conditions. The grade is characterized by:

  • Very good resistance to sulphide stress cracking and stress corrosion cracking (SCC) in chloride and sour (H2S/Cl-) environments
  • Very high resistance to pitting and crevice corrosion

Standards

  • UNS N08028
  • ISO 4563-080-28-I

Product standards

Seamless tubes used as casing, tubing and coupling stock: ISO 13680, PSL-1 and PSL-2

Approvals

  • NACE MR0175/ISO 15156 (Petroleum and natural gas industries - Materials for use in H2S-containing environments in oil and gas production)

Chemical composition (nominal) %

C
max
Si
max
Mn
max
P
max
S
max
Cr Ni Mo Cu
0.020 0.6 2.0 0.025 0.015 27 31 3.5 1.0

Forms of supply

Materials for oil and gas production

Cold worked seamless tube and pipe

For production tubing, casing, liner, and coupling stock for downhole oil and gas applications, Sanicro 28 is supplied cold worked with high strength properties. (Sanicro 28-110ksi, -125ksi)

Full details on sizes, finishes and mechanical properties are available on request.
Email: stmo.smt@sandvik.com

Mechanical properties

At 20°C (68°F)

Metric units and Imperial units
Grade Proof strength Tensile strength Elong. Hardness
Rp0.2a) Rm A2" HRC
MPa ksi MPa ksi %
min min min max
PSL-1 Sanicro 28-110 760 - 965 110 - 140 795 115 11 35
PSL-1 Sanicro 28-125 860 - 1035 125 - 150 895 130 10 37
PSL-2 Sanicro 28-110 760 - 965 110 - 140 795 115 11 33
PSL-2 Sanicro 28-125 860 - 1000 125 - 145 895 130 10 35

1 MPa = 1 N/mm2
a) Rp0.2 correspond to 0.2% offset yield strength.

At high temperatures

Cold-worked Sanicro 28 also displays very good mechanical properties at higher temperatures. Further information is available on request. Email:stmo.smt@sandvik.com

Metric units Imperial units
Temperature, °C De-rating factor* Temperature, °F De-rating factor*
20 1.00 68 1.00
50 0.97 100 0.98
100 0.92 200 0.93
150 0.89 300 0.89
200 0.88 400 0.88
250 0.87 500 0.87

*) Approximate yield strength at temperature is received by multiplying the corresponding de-rating factor and yield strength at 20oC (68oF).

Impact strength

Due to its austenitic microstructure, Sanicro 28 has very good impact strength, both at room temperature and at lower temperatures. Tests have demonstrated that the steel readily fulfills the requirements in accordance with ISO 13680 (min. 40 J at -10oC (50oF)).

Physical properties

Physical properties of cold-worked Sanicro 28.

Density: 8.0 g/cm3, 0.29 lb/in3

Metric units Imperial units

Thermal conductivity
Metric units Imperial units
Temperature, °C W/(m °C) Temperature, °F Btu/(ft h °F)
20 11 68 6.5
50 11 100 6.5
100 12 200 7
150 13 300 7.5
200 14 400 8.5
250 15 500 9
300 16 600 9.5
Specific heat capacity
Metric units Imperial units
Temperature, °C J/kg °C Temperature, °F Btu/lb °F
20 460 68 0.11
50 470 100 0.11
100 480 200 0.12
150 495 300 0.12
200 505 400 0.12
250 515 500 0.12
300 525 600 0.13
Resistivity
Metric units Imperial units
Temperature, °C µΩm Temperature, °F µΩin.
20 0.98 68 38.7
100 1.00 200 39.3
150 1.00 300 39.4
200 1.01 400 39.9
250 1.04 500 41.3
300 1.10 600 44.2
Thermal expansion 1)
Metric units Imperial units
Temperature, °C Per °C Temperature, °F Per °F
30-50 13 86-120 7.5
30-100 14.5 86-200 8
30-150 15 86-300 8.5
30-200 15.5 86-400 8.5
30-250 15.5 86-500 8.5
30-300 15.5 86-600 8.5

1) Mean values in temperature ranges (×10-6)

Modulus of elasticity 1)
Metric units Imperial units
Temperature, °C MPa Temperature, °F ksi
20 195 68 28.3
100 190 200 27.6
200 182 400 26.3
300 174 600 25.1

1) (×103)

Poisson´s ratio

The Poisson's ratio is 0.29 for Sanicro 28 at room temperature.

Corrosion resistance

Pitting corrosion

Sanicro 28 can withstand high temperatures in aggressive environments without pitting. A recognised method of ranking a material's susceptibility to localized corrosion is by means of the PRE number (Pitting Resistance Equivalent). This PRE number is based on the contents of chromium, molybdenum and nitrogen in the alloy according to the following formula:
PRE = %Cr + 3.3 × %Mo + 16 × %N

A PRE number is the relative measure of a material's ability of preventing pitting corrosion in chloride containing environments. Sanicro 28 has a minimum PRE number of 38, which confirms its high resistance to pitting corrosion when chlorides are present.

Potentiostatic tests based on ASTM G150 on cold-worked Sanicro 28 in solutions with different chloride concentrations and different pH values are presented in Figure 1 and Figure 2, respectively. In these tests the critical pitting temperature (CPT) is determined in oxidizing conditions at the potential of +600 eV versus SCE. However, the conditions in the well are significantly less oxidizing, resulting in actual CPT values in the wells being higher than those presented in the figures.

Figure 1. Critical pitting temperature (CPT) as a function of chloride concentration for cold-worked Sanicro 28. The potential was +600 mV vs. SCE.

Figure 2. Critical pitting temperature (CPT) as a function of pH for cold worked Sanicro 28 in a 3% Cl- solution. The potential was +600 mV vs. SCE.

Stress corrosion cracking

Environmental assisted cracking, especially in the presence of hydrogen sulphide (H2S), is one of the more serious forms of corrosion in sour environments. Failure of tubing by environmental assisted cracking can occur rapidly without any warning. For that reason, the prevention of this form of corrosion must be considered when selecting tubing materials for sour wells.

Sanicro 28 possesses very good resistance to environmental assisted cracking in conditions where hydrogen sulphide is present together with chlorides. The high corrosion resistance of Sanicro 28 has been proven by laboratory tests and confirmed in actual production environments.

Figure 3 presents the results of constant load tests according to NACE TM0177-2005 at different temperatures and partial pressures of hydrogen sulphide. In some cases, the limitation are those of the test equipment and not the material.

Figure 3: Constant load tests of cold-worked Sanicro 28 at 100% of the actual yield strength. The concentration of NaCl in the brine is 15% and the partial pressure of CO2 is 1000 psi. The grey line represents the approved environments according to NACE MR0175/ISO 15156-3 for the 4c type materials.

Stress corrosion cracking tests have also been performed in the presence of elemental sulfur. Cold worked Sanicro 28 tube with an Rp0.2 value of 889 MPa (129 ksi) has been tested. The tests were performed, according to NACE TM0177-2005, with tensile specimens stressed to 100% of the actual yield strength.

Temperature pH2S pCO2, psi Chlorides (Cl-) Elemental sulfur Stress corrosion cracking
°C (°F) psi (MPa) (MPa) ppm g/L
140 (284) 2200 (15.2) 1000 (6.9) 91000 1 No
160 (320) 2200 (15.2) 1000 (6.9) 91000 1 No
170 (338) 2200 (15.2) 1000 (6.9) 91000 1 No
160 (320) 2200 (15.2) 1000 (6.9) 225000 1 No

Heat treatment

Tubes for downhole oil and gas applications are delivered in the high strength, cold worked condition. They are not annealed after cold working.

Fabrication

Sanicro 28 tubes are supplied in the cold worked condition and are intended for use with threaded connections.

Applications

Sanicro 28 is used for high strength downhole production tubing, casing, and liners in sour gas wells. This includes environments with high temperatures, high partial pressures of CO2 and H2S, and high chloride concentrations.

Disclaimer: Recommendations are for guidance only, and the suitability of a material for a specific application can be confirmed only when we know the actual service conditions. Continuous development may necessitate changes in technical data without notice. This datasheet is only valid for Sandvik materials.

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