Sandvik Materials Technology is a developer and producer of advanced stainless steels, special alloys, titanium and other high-performance materials

Sandvik 6R35 (Tube and pipe, seamless)

Datasheet updated 2013-03-22 15:41:18 (supersedes all previous editions)

Sandvik 6R35 is an austenitic, titanium-stabilized stainless chromium-nickel steel. It is suitable for wet-corrosive service but also has good mechanical strength at high temperatures.

Standards

  • ASTM TP321, TP321H
  • UNS S32100, S32109
  • EN number 1.4541, 1.4940
  • EN name X6CrNiTi18-10, X7CrNiTi18-10
  • W.Nr. 1.4541, 1.4878
  • DIN X6CrNiTi 18 10, X12CrNiTi 18 9
  • SS 2337
  • AFNOR Z6CNT18-10
  • BS 321S31, 321S51

Product standards

Seamless tube and pipe

  • ASTM A213, A312, A269, A376, (A511)
  • EN 10216-5
  • BS 3059, 3605, 3606
  • DIN 17456, 17458
  • SS 14 23 37
  • NFA 49-117, 49-217

Chemical composition (nominal) %

C Si Mn P S Cr Ni Ti
max max
0.05 0.5 1.3 0.030 0.030 17.5 10.5 >5xC

Forms of supply

Seamless tube and pipe-Finishes and dimensions

Seamless tube and pipe in Sandvik 6R35 is supplied in dimensions up to 260 mm outside diameter in the solution-annealed and white-pickled condition or solution-annealed in a bright-annealing process.

Hollow bar

Hollow bars are supplied solution-annealed and white-pickled.

Sizes in stock

Seamless tube and pipe
Seamless tube and pipe are stocked in a wide range of sizes according to ISO and ANSI both in hot extruded as well as in the cold finished and annealed condition. Details of our manufacturing and stock programme are given in catalogue S-110-ENG.

Hollow bar
Hollow bar is stocked in large number of sizes. Our standard size range for stock comprises 32-250 mm (1.3-9.8 in.) O.D. See catalogue S-110-ENG.

Filler metal for welding
The sizes listed below are Sandvik stock standard. The local stocks carry sizes in common demand on the market. For technical information on the filler metals please refer to brochures S-2361-ENG and S-2362-ENG.

Welding wire/rod
Sandvik 19.9.NbSi: 0.80, 1.00, 1.20, 1.60 mm diameter
Sandvik 19.9.LSi: 0.80, 1.00, 1.20, 1.60 mm diameter

Covered electrodes
Sandvik 19.9.LR: 1.60, 2.00, 2.50, 3.25, 4.00 mm diameter

Mechanical properties

At 20°C (68°F)

Proof strength Tensile strength Elong. Hardness
Rp0.2a) Rp1.0a) Rm Ab) HRB
MPa ksi MPa ksi MPa ksi %
min min min min min max
210 30 240 35 515-690 75-100 35c) 90

1 MPa = 1 N/mm2
a) Rp0.2 and Rp1.0 correspond to 0.2% offset and 1.0% offset yield strength, respectively.
b) Based on L0 = 5.65 √S0 where L0 is the original gauge length and S0 the original cross-section area.
c) NFA 49-117 and NFA 49–217 with min 45% can be fulfilled.

Impact strength

Due to its austenitic microstructure, Sandvik 6R35 has very good impact strength both at room temperature and at cryogenic temperatures.

Tests have demonstrated that the steel fulfils the requirements (60 J (44 ft-lb) at -196 oC (-320 oF)) according to the European standards prEN 13445-2 (UFPV-2) and prEN 10216-5.

At high temperatures

Metric units
Temperature
Proof strengthc)
Rp0.2 Rp1.0
°C MPa MPa
min min
50 195 230
100 180 210
150 170 195
200 160 185
250 150 180
300 140 175
350 135 170
400 130 165
450 130 165
500 125 160
550 125 160
600
120
155
Imperial units
Temperature
Proof strengthc)
Rp0.2 Rp1.0
°F ksi ksi
min min
200 26.0 30.5
400 22.5 26.5
600 19.5 25.0
800 18.5 23.5
1000 17.5 23.0
1100
17.0
22.0

c) For extruded tube and pipe with wall thickness greater than 10 mm (0.4 in.) the proof strength may fall short of the stated value by 20 MPa (2.9 ksi) at 100°C (200°F) and by 10 MPa (1.4 ksi) in the temperature range 200-600°C (400-1100°F).

Creep rupture strength
Temperature 10 000 h 100 000 h
°C °F MPa ksi MPa ksi
approx. approx. approx. approx.
550 1020 234 34.0 184 26.7
575 1065 175 25.4 126 18.3
600 1110 143 20.7 94 13.6
625 1155 110 16.0 75 10.9
650 1200 90 13.1 58 8.4
675 1245 76 11.0 48 7.0
700 1290 59 8.6 39 5.7
750 1380 29 4.2 16 2.3

Physical properties

Density: 7.9 g/cm3, 0.29 lb/in3

Thermal conductivity
Temperature, °C W/m °C Temperature, °F Btu/ft h °F
20 14 68 8
100 15 200 8.5
200 17 400 10
300 19 600 11
400 21 800 12
500 22 1000 13
600 24 1200 14
700 25 1400 15
800 26 1600 16
900 28 1800 16.5
1000 29 2000 17.5
1100 30
Specific heat capacity
Temperature, °C J/kg °C Temperature, °F Btu/lb °F
20 465 68 0.11
100 490 200 0.12
200 515 400 0.12
300 540 600 0.13
400 560 800 0.14
500 580 1000 0.14
600 595 1200 0.14
700 610 1400 0.15
800 625 1600 0.15
900 640 1800 0.16
1000 650 2000 0.16
1100 665
Thermal expansion 1)
Temperature, °C Per °C Temperature, °F Per °F
30-100 17.5 86-200 9.5
30-200 17.5 86-400 10
30-300 18 86-600 10
30-400 18 86-800 10
30-500 18.5 86-1000 10.5
30-600 18.5 86-1200 10.5
30-700 19 86-1300 10.5

1) Mean values in temperature ranges (x10-6)

Modulus of elasticity 1)
Temperature, °C MPa Temperature, °F ksi
20 200 68 29.0
100 194 200 28.2
200 186 400 26.9
300 179 600 25.8
400 172 800 24.7
500 165 1000 23.5

1) (x103)

Corrosion resistance

General corrosion

Sandvik 6R35 has with some limitations (nitric acid) the same resistance as the unstabilised steel AISI 304. Consequently, the grades have good resistance to

  • Organic acids at moderate temperatures
  • Salt solutions, e.g. sulphates, sulphides and sulphites
  • Caustic environments at moderate temperatures

Intergranular corrosion

The stabilisation with titanium gives Sandvik 6R35 improved resistance to intergranular corrosion.

Pitting and crevice corrosion

Pitting and crevice corrosion may occur even in solutions of relatively low chloride content. However, the stabilisation with titanium results in a somewhat better resistance than that of AISI 304.

Stress corrosion cracking

Austenitic steels, like 6R35 are susceptible to stress corrosion cracking. This may occur at temperatures above about 60 °C (140 °F), if the material is subjected to tensile stresses and at the same time comes into contact with certain solutions, particularly those containing chlorides. Such service conditions should therefore be avoided. Conditions when plants are shut down must also be considered as the condensates which are then formed can develop a chloride content that leads to both stress corrosion cracking and pitting.

In applications demanding high resistance to stress corrosion cracking we recommend the austenitic-ferritic steel Sandvik SAF 2304. See data sheet S-1871-ENG.

Gas corrosion

Sandvik 6R35 can be used in

  • Air up to 850°C (1560°F)
  • Steam up to 750°C (1380°F)
  • Synthesis gas (ammonia synthesis) up to about 550 °C (1020 °F)

Creep should also be taken into account when using the steel in the creep range.

In flue gases containing sulphur, the corrosion resistance is reduced. in such environments this steel can be used at temperatures up to 600-750 °C (1110-1380 °F) depending on service conditions. Factors to consider are whether the atmosphere is oxidising or reducing, i.e. the oxygen content, and whether impurities such as sodium and vanadium are present.

Heat treatment

The tubes are normally delivered as described above. If additional heat treatment is needed after further processing the following is recommended.

Solution annealing

Tp 321

1040-1100°C (1905-2010°F), 2-5 min, rapid cooling in air or water.

Tp321H

Stabilisation treatment: 1040-1100°C (1920-2010°F), 2-5 min rapid cooling in air or water. However, annealing above 1100°C (2010°F) may be required in order to meet grain size requirements. This treatment should be followed by a stabilisation treatment.

Stress relieving

850-950°C (1560-1740°F), 10-15 minutes, cooling in air.

Welding

The weldability of Sandvik 6R35 is good. Suitable welding methods are manual metal-arc welding with covered electrodes and gas-shielded arc welding with the TIG and MIG methods as first choice. Preheating and post-weld heat treatment are not normally necessary.

Since the material has low thermal conductivity and high thermal expansion, welding must be carried out with a low heat input and with welding plans well thought out in advance so that the deformation of the welded joint can be kept under control. If, despite these precautions, it is foreseen that the residual stresses might impair the function of the weldment, we recommend that the entire structure be stress relieved.

As filler metal for gas-shielded arc welding we recommend wire electrodes and rods Sanicro 72. In manual metal-arc welding covered electrodes Sanicro 72 are recommended. For application at temperatures up to 400°C (750°F) also welding wire/rod Sandvik 19.9.NbSi, 19.9.Nb, 19.9.LSi or 19.9.L and covered electrodes Sandvik 19.9.NbR or 19.9.LR are recommended.

Bending

Annealing after cold bending is not normally necessary, but this point must be decided with regard to the degree of bending and the operating conditions. Heat treatment, if any, should take the form of stress-relieving or solution annealing.

Hot bending is carried out at 1100-850°C (2010-1560°F) and should be followed by solution annealing.

Machining

Sandvik 6R35 has good machining properties. Detailed recommendations for the choice of tools and cutting data are provided in the printed matter S-1492-ENG.

Applications

Good resistance to hydrogen sulphide gas and intergranular corrosion coupled with good high temperature strength make Sandvik 6R35 a suitable material for applications as tubes in heating furnaces and heat exchangers in sulphurisation and hydro-treating plants. In the petrochemical industry the steel is used in cracking furnaces for the production of ethylene and vinyl chloride. It is also frequently used for heat exchangers and piping in the chemical and petrochemical industries.

Disclaimer: Recommendations are for guidance only, and the suitability of a material for a specific application can be confirmed only when we know the actual service conditions. Continuous development may necessitate changes in technical data without notice. This datasheet is only valid for Sandvik materials.

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